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Reference model (2009 kinetics)

How to simulate ethylene oxide hydration to mono-ethylene glycol (meg)

Ethylene oxide reacts uncatalyzed with excess water at 200 C to mono-ethylene glycol (MEG, antifreeze/PET feedstock); the excess-water dilution that suppresses the over-reaction to di-/tri-ethylene glycol byproducts is reflected in the large water excess on the feed, and a downstream column concentrates MEG in the bottoms while excess water leaves overhead for recycle. Kinetics basis: Ind. Eng. Chem. Res. 2009, 48, 10840.

Also known as: MEG plant, mono-ethylene glycol unit, EO hydration to glycol.

Eofeed
Waterfeed
MIX
RXN
COOL
Degas
EO VENT
feed
dist
btms
Qc
Qr
COL
Water Recycle
MEG Product
  1. 1
    Open the ready-made model

    Open the "Ethylene oxide hydration to mono-ethylene glycol (MEG)" model in the MaximaLabs workspace — no install, no license. It loads live on the canvas, ready to edit and run.

  2. 2
    Confirm the thermodynamics

    This process is modeled with the PENG-ROBINSON property package over ethylene_oxide, water, ethylene_glycol — already selected, so the phase equilibrium and enthalpy are physically consistent from the first run.

  3. 3
    Review the flowsheet

    The flowsheet chains MIX, RXN, COOL, Degas, COL. Every block is a real, solvable unit op you can reconfigure on the canvas.

  4. 4
    Run the simulation

    Click Run. The deterministic solver converges the material and energy balances (recycles included) and fills the live stream table — the AI never invents a number.

  5. 5
    Read the results and iterate

    Inspect the converged streams, tweak a spec, and re-run — or ask the AI copilot to explain a result or diagnose a failed solve in plain English.

What you'll build
Thermodynamics
PENG-ROBINSON
Components
ethylene_oxide, water, ethylene_glycol
Unit operations
MIXRXNCOOLDegasCOL
Open this model in the workspace

Opens live on the canvas — free, no install.

Explore the model & flowsheet

Frequently asked questions

What does the Ethylene oxide hydration to mono-ethylene glycol (MEG) model simulate?
Ethylene oxide reacts uncatalyzed with excess water at 200 C to mono-ethylene glycol (MEG, antifreeze/PET feedstock); the excess-water dilution that suppresses the over-reaction to di-/tri-ethylene glycol byproducts is reflected in the large water excess on the feed, and a downstream column concentrates MEG in the bottoms while excess water leaves overhead for recycle. Kinetics basis: Ind. Eng. Chem. Res. 2009, 48, 10840.
Is "Ethylene oxide hydration to mono-ethylene glycol (MEG)" the same as a MEG plant?
Yes — this model covers what is also called MEG plant, mono-ethylene glycol unit, EO hydration to glycol. It runs the real process on the rigorous solver, so you can size and study it directly.
Which thermodynamic method does it use?
The PENG-ROBINSON property package, over ethylene_oxide, water, ethylene_glycol — already selected. You can switch the method on the canvas before running.
Which unit operations are in the flowsheet?
It chains MIX, RXN, COOL, Degas, COL. Every block is a real, solvable unit operation you can reconfigure, add to, or remove.
Do I need to install software or buy a license?
No. Ethylene oxide hydration to mono-ethylene glycol (MEG) runs entirely in your browser on MaximaLabs — free, no install, no license. Open the model to load it live and run the deterministic solver.

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The full EO/MEG chain in one flowsheet, upstream of the standalone hydration example: ethylene and oxygen react over a silver catalyst to ethylene oxide (low per-pass ethylene conversion, ~10%, is realistic — high conversion pushes the competing total-combustion side reaction, which this model represents as a second reactor consuming a fixed share of the same ethylene at ~80% EO selectivity). A cooled flash condenses EO (and reaction water) from the unreacted ethylene/oxygen/CO₂ vented for combustion-side purge; the condensed EO then hydrates with fresh water to MEG exactly as in the standalone hydration example. No ethylene/O₂ recycle loop (an honest simplification — real plants recycle unreacted ethylene at high ratio).

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