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Adsorption Process Flowsheets & Simulations

Explore 4 validated, solved Adsorption simulation flowsheets in MaximaLabs — real components: h2, co2, ammonia, n2, oxygen, argon. Open any one directly in your browser.

Solved via: PENG-ROBINSON.

FEED
PSA
Product
TAIL GAS
Steam-methane-reforming H2 plant, Air Products, Rotterdam, Netherlands

Pressure Swing Adsorption — H2 purification

A 5 bar shift-gas feed (H₂/CO₂, the dominant impurity leaving a steam-methane-reforming shift reactor) is purified across a real cyclic 2-bed PSA unit: while one bed adsorbs CO₂ at high pressure (delivering H₂-rich product), the other regenerates at low pressure, swept countercurrently by a slipstream of that product to desorb CO₂ out the feed end as tail gas — the genuine Skarstrom-cycle mechanism, not a fixed-recovery shortcut. The solver runs the real cyclic transient (tanks-in-series bed discretization + linear-driving-force adsorption kinetics toward the same competitive-Langmuir isotherm uses) to a periodic steady state.

4 unit ops • PENG-ROBINSON

225 0

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Fast convergence
NH3 FEED
Cracker
PSA
H2 Product
TAIL GAS
Reference model (screening)

Ammonia cracking + H2 purification

Green ammonia is a widely proposed hydrogen carrier for shipping — easier to liquefy and transport than liquid H₂ itself, then cracked back to H₂ at the point of use. A fixed-conversion reactor dissociates NH₃ (2 NH₃ → N₂ + 3 H₂, endothermic, 99% conversion at a typical 600 C cracking-furnace outlet) and the cracked gas is polished by an adsorption stage to fuel-cell-grade H₂.

5 unit ops • PENG-ROBINSON

223 0

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⭐ Featured
AIR
VPSA
Oxygen
TAIL GAS
Direct-reduced-iron (green steel) plant, Boden, Sweden

On-site oxygen: multi-bed vacuum pressure swing adsorption (VPSA)

Medical- / green-steel-grade oxygen generated on site from air by a 4-bed vacuum pressure swing adsorption unit over an N₂-selective zeolite (LiX/13X). This uses the native VPSA unit op — the proven 2-bed Skarstrom engine generalized to N beds with pressure-equalization steps and sub-atmospheric evacuation: nitrogen is adsorbed while oxygen passes as the light product, then each bed is pulled to a vacuum to desorb the nitrogen tail gas. The solver runs the real cyclic transient (tanks-in-series bed discretization + linear-driving-force kinetics + inter-bed equalization) to a periodic steady state — the transient dynamic equilibrium legacy steady-state simulators cannot capture without a separate dynamic license.

4 unit ops • PENG-ROBINSON

223 0

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Illustrative flue-gas adsorption capture unit

Flue-gas CO2 capture by solid-sorbent adsorption

A generic solid-sorbent (zeolite-13X-class) adsorption capture step on real combustion flue gas (13 mol% CO₂ — typical of a natural-gas- or coal-fired flue gas, a much higher CO₂ partial pressure than direct-air-capture's ~400 ppm case, which is why this uses the existing Adsorption unit op's real competitive-Langmuir isotherm directly on the flue-gas stream rather than the fixed-recovery separator shortcut the existing DAC examples use). Adsorption-based flue-gas capture is a real, generically licensed technology category (Linde's HISORP CC targets exactly this application); the isotherm parameters here are representative order-of-magnitude values for a zeolite-13X-class sorbent's CO₂/N₂/O₂/H₂O selectivity (real published 13X studies show CO₂ adsorbing roughly an order of magnitude more strongly than N₂/O₂, and water more strongly still, competing for capacity), not pinned to one specific cited paper's exact figures — disclosed as representative, matching MaximaLabs's convention when a precise source isn't confidently pinnable, rather than presenting invented precision. Adsorbent inventory (adsorbent_mass) is sized to a real, honest ~96% CO₂ capture rate — not assumed/rounded to a marketing-friendly number.

4 unit ops • PENG-ROBINSON

189 2

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