Cryogenics Process Flowsheets & Simulations
Explore 14 validated, solved Cryogenics simulation flowsheets in MaximaLabs — real components: n2, methane, ethane, propane, water, n_butane. Open any one directly in your browser.
Solved via: PENG-ROBINSON, COOLPROP.
C3MR LNG liquefaction
A simplified APCI C3MR train: natural gas and the mixed refrigerant are precooled by a closed propane loop, liquefied to 120 K in a multi-stream main cryogenic exchanger against a closed N₂/C₁/C₂/C₃ refrigerant cycle, then let down to storage — LNG at ~115 K. Single-level precool and a single MCHE bundle (a real train uses three propane levels and two bundles); refrigerant charges are set via tear_specs.
13 unit ops • PENG-ROBINSON
226 0
View & openLNG front end and storage: guard beds, tank boil-off, driver limit
The parts of a 5.2 Mtpa LNG train that are not the cold box, and the four questions they answer that no bulk unit can — at real capacity, so the vessel sizes and duties are ones an engineer can check against their own plant. Guard beds: a sulfur-carbon bed takes mercury from 200 to 0.01 µg/Nm³ — the brazed-aluminium limit, because mercury attacks the plate-fin cold box by liquid-metal embrittlement — on a 4.8 m x 6.6 m bed with 4.2 years of life from a capacity balance — inside the 3-5 year window these non-regenerable beds are actually replaced on, which is what a turnaround plan needs. A 4A molecular sieve then dries the gas to 0.1 ppmv, the only route to a cryogenic water spec (a glycol contactor tops out near a −30 °C dew point), on a 4.9 m x 5.1 m bed running a 13.8 h cycle for 1.3 MW of regeneration duty. Storage: the LNG goes to a tank whose boil-off rate comes from a 0.05%/day guarantee but whose boil-off composition comes from a real equilibrium flash — and that is the interesting part, because the vapour leaves at ~11 mol% nitrogen against 1.1% in the feed. Nitrogen and methane are far more volatile at 113 K, so the boil-off is light and the stored liquid weathers heavier: nobody specified that, the flash found it. Recondensing: the boil-off goes back into the send-out LNG rather than to a flare, and the unit reports the LNG:BOG ratio (1999) against the minimum the energy balance demands (3.8), which is the constraint a terminal is actually operated against. The driver: a gas turbine burning plant fuel gas, rated 97.5 MW at ISO conditions, delivers only 84.5 MW at 35 °C — 5.5 MW short of its 90 MW refrigeration load, and flagged as such. That derate is computed from two physical effects (a fixed-geometry compressor swallows a fixed volume so mass flow follows air density, and hotter air costs more to compress), not from a vendor curve, and it comes out at 0.66%/K — mid-band for industrial machines. It is why a tropical LNG train makes less product in summer.
17 unit ops • PENG-ROBINSON
107 0
View & openGas-condensate LNG train: condensate, LPG and LNG
The LNG plant that is also a liquids plant, at real capacity: this is one 4.4 Mtpa train (a two-train plant is two of these), not a scaled-down sketch. A condensate-rich field arrives by trunkline as a two-phase stream: the slug catcher drops ~20 mol% of it out as raw condensate before a single molecule reaches the cold end, and the plant then runs two trains side by side off one feed. Liquids: the raw condensate is let down to an MP flash that strips the dissolved methane (without it the stabilizer's shortcut total condenser tries to condense methane at 8 bar, which is not a real stabilizer overhead), then stabilized to a C₅/C₆ product. Gas: sweetened and dried, chilled to 245 K to knock out an NGL cut, and the NGL demethanized and split by a deethanizer / depropanizer / debutanizer sequence into commercial propane (~98 mol%) and butane (~98 mol%) LPG plus a natural-gasoline bottoms. LNG: the lean gas goes to the same APCI C3MR cold end as the 'c3mr-lng-liquefaction' showcase — propane precool, mixed-refrigerant MCHE to 120 K, JT letdown to a 1.5 bar end-flash drum. Five sold products come out of one flowsheet, each a stream the solver computed. Watch the end-flash boil-off: it leaves at ~13 mol% nitrogen against 1 mol% in the feed, because the flash drum is where an LNG train actually rejects its nitrogen — nobody specified that, the flash found it. Dehydration is the real molecular-sieve bed, not a stand-in: a 4A sieve sized by length-of-unused-bed, which is what actually takes the gas to the <=0.1 ppmv the cold box needs — 95 t of sieve on a 5.5 x 5.5 m bed, a 17.5 h cycle and 1.4 MW of regeneration duty, with 0.47 bar of Ergun pressure drop. The AGRU spec is checked against the physics rather than assumed: 99.9% CO₂ removal leaves 33 ppmv, and at the coldest point in the train (115.9 K) the solid-CO₂ solubility limit is 232 ppmv on the measured-data basis — a 7x margin, so the sweetening spec demonstrably clears freeze-out instead of merely looking tight.
35 unit ops • PENG-ROBINSON
109 1
View & openHigh-CO2 LNG with amine capture and CO2 reinjection
One 5.3 Mtpa LNG train on a reservoir whose gas is 14 mol% CO₂, where the CO₂ is not vented but compressed to dense phase and injected — 2.8 Mtpa of it, at 200 bar, which is the scale that makes this a storage project rather than a gesture. Two things make this different from every other LNG example here. First, the acid-gas removal is real chemistry, in the same flowsheet as the cryogenics: per-node thermo_overrides run the absorber, the rich/lean loop and the stripper on the 'enrtl-mdea-pz' electrolyte package (MDEA protonation + piperazine carbamate/dicarbamate speciation) while the gas train and the cold end run Peng-Robinson — the amine unit and the MCHE are not two models bolted together, they are one solve. Second, the CO₂ goes somewhere: the stripper overhead is knocked back, two-stage compressed with interstage cooling and drying, and pumped to 200 bar as a ~96 mol% dense-phase stream ready for a reinjection well, rather than leaving as a vent. The sweet gas is water-washed, dried and liquefied in the C3MR cold end to LNG at ~116 K.
32 unit ops • PENG-ROBINSON
108 0
View & openTwo-stage cascade (−100 °C)
Propylene + ethylene cascade: the ethylene loop condenses inside a heat exchanger against the evaporating propylene loop and serves a −100 °C load. Two coupled closed cycles. From the ChemSep casebook (Refrigeration_2-Stage-100C).
7 unit ops • PENG-ROBINSON
224 0
View & openThree-stage cascade (−150 °C)
Propylene → ethylene → methane cascade to −150 °C: each colder loop condenses against the next-warmer loop’s evaporator. From the ChemSep casebook (Refrigeration_3-Stage-150C).
10 unit ops • PENG-ROBINSON
224 0
View & openFour-stage cascade (≈−190 °C)
Propylene → ethylene → methane → nitrogen cascade reaching ≈81 K — four coupled closed loops, the full ChemSep cascade ladder (Refrigeration_4-Stage-190C). Air-separation-grade cold from stacked vapor-compression cycles.
13 unit ops • PENG-ROBINSON
223 0
View & openTEALARC LNG liquefaction
A simplified Technip TEALARC train: two closed mixed-refrigerant loops — a heavy C₁/C₂/C₃ precool MR that also cools itself in a 4-stream exchanger, and a light N₂/C₁/C₂/C₃ liquefaction MR — bring natural gas to 120 K before letdown to storage (LNG at ~115 K). Both circulations are set via tear_specs; the precool MR runs rich for pinch feasibility (screening fidelity). From the ChemSep casebook (TEALARC).
13 unit ops • PENG-ROBINSON
224 1
View & openHelium liquefaction (Linde-Hampson cycle)
A Joule-Thomson liquefaction loop: helium is compressed, aftercooled, precooled well below its ~40-51 K JT-inversion temperature, then throttled through a valve into a flash drum that draws off liquid helium while the cold vapor recycles back to the compressor suction — the same JT-cycle physics as the platform's LNG/refrigeration loops, run on a fluid whose inversion curve makes precooling mandatory before the throttle can cool it at all.
8 unit ops • COOLPROP
222 0
View & openSnohvit mixed-fluid-cascade LNG liquefaction
A simplified Statoil/Linde MFC train: three independent, cascaded closed refrigerant loops (propane precool, an N₂/methane/ethane liquefaction MR, and an N₂/methane subcooling MR) each condense/precool through the previous stage's cold box before their own JT expansion — the same cross-stage coupling TEALARC uses, one level deeper. Natural gas is cooled 300 K → 255 K → 175 K → 112 K across the three multi-stream exchangers before letdown to LNG storage (~114 K). All three circulations are set via tear_specs. From the ChemSep casebook (Snohvit MFC).
17 unit ops • PENG-ROBINSON
226 0
View & openFLNG dual N2-expander liquefaction
A reverse-Brayton (turboexpander, not vapor-compression) liquefaction train — the compact, offshore-friendly FLNG alternative to mixed-refrigerant cycles like C3MR. Natural gas is acid-gas-scrubbed and mol-sieve-dried (fixed-recovery separators, the same simplification the existing carbon-capture example uses for amine treating), then cooled in two cascaded closed nitrogen loops: a warm loop precools the gas and the cold loop's own N₂ charge, and a cold loop finishes the liquefaction to ~113 K in a main cryogenic multi-stream exchanger. Both loops are pure compressor + turboexpander cycles — no phase change in the refrigerant, no JT valves — the real differentiator from every other LNG example here. Single precool level and a single MCHE bundle (a real train uses more); refrigerant charges are set via tear_specs.
17 unit ops • PENG-ROBINSON
223 1
View & openCryogenic helium recovery / nitrogen rejection
A helium-rich natural gas is let down through a real isentropic turboexpander, then cascaded through two cryogenic flash stages (125 K, then 105 K) that progressively concentrate helium in the vapor while methane and nitrogen condense out.
11 unit ops • PENG-ROBINSON
223 0
View & openHydrogen liquefaction with catalytic ortho-para conversion
A Linde-Hampson JT-cycle liquefaction loop for H₂ (the same recycle topology as helium-liquefaction), but H₂'s real liquefaction process needs one more step helium doesn't: normal H₂ feed is ~75% ortho-/25% para-spin-isomer, while the equilibrium mix at liquid-H₂ temperature is ~99.8% para — liquefying without converting first leaves the ortho fraction far above its new equilibrium value, and its slow natural relaxation releases heat (the textbook explanation for uncatalyzed LH2 tanks self-boiling). This closes a real gap: (a catalytic cold-box converter, real equilibrium-para-fraction statistical mechanics) existed in MaximaLabs but was never wired into a showcase example — and turned out to also be missing from the backend's unit-type validation catalog entirely (fixed alongside this example,). Precooling to 30 K (deep enough that H₂'s JT effect actually condenses it — verified numerically: 77 K/60 K/45 K precool all give zero liquid yield at 20 atm → 1.3 atm here, since H₂'s JT-cooling window needs real precooling well below LN2 temperature, unlike simpler gases) also happens to sit right where the ortho-para conversion actually matters.
9 unit ops • COOLPROP
191 1
View & openLNG regasification via submerged combustion vaporizer
A real LNG-terminal regasification technology: fuel gas burns submerged in a water bath, and the hot combustion products bubbling through that bath transfer heat (via submerged tube coils) to vaporize the incoming LNG — no new unit-op physics needed here, since MaximaLabs's existing fired_heater already models exactly the energy balance this needs (Q_process = efficiency * Q_released from real fuel-gas combustion stoichiometry, then a duty-driven (P,H) flash on the process-side stream) and doesn't care whether that process stream starts liquid or vapor — feeding it cryogenic liquid methane and specifying a target outlet temperature above its boiling point genuinely vaporizes it through the same mechanism.
5 unit ops • PENG-ROBINSON
188 1
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