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Electrolyte thermo Process Flowsheets & Simulations

Explore 2 validated, solved Electrolyte thermo simulation flowsheets in MaximaLabs — real components: water, nacl, li, mg, lioh. Open any one directly in your browser.

Solved via: BRINE.

Seawater
PUMP
RO
Fresh
Steam
feed
steam
conc
vapor
cond
CONC
CONC Condensate
CONC Vapor
feed
solid
liq
ZLD
SALT
Brine
Carlsbad, California, USA

RO desalination + ZLD

Seawater (real NaCl brine, Pitzer-electrolyte thermo) is pressurized and split in a reverse-osmosis membrane into fresh permeate and concentrate; a thermal brine concentrator (an evaporator effect) drives the concentrate the rest of the way to saturation — RO alone can't reach it, since retentate osmotic pressure would exceed any practical feed pressure — before a crystallizer closes the zero-liquid-discharge loop on solid NaCl. The membrane's recovery is bounded by the retentate's real osmotic pressure.

11 unit ops • BRINE

17 0

View & open
Brine
DLE
Spent Brine
Eluent
Elute MIX
RO PUMP
RO
RO Permeate
BPED
Steam1
feed
steam
conc
vapor
cond
Evap1
feed
steam
conc
vapor
cond
Evap2
Evap1 Condensate
Evap2 Condensate
feed
solid
liq
Cryst
LIOH Product
Mother Liquor
Salar de Atacama, Chile

Direct lithium extraction + LiOH crystallization

A Salar-brine DLE train: an Al-based sorbent column selectively loads Li+ (rejecting the brine's much larger Mg2+ background — real DLE sorbents cut a ~290:1 Mg/Li mass ratio down to under 1:1), the loaded sorbent is eluted with fresh water into an aqueous strip liquor (bridging the sorption column's own documented single-pass-loading scope), RO concentrates it, a real bipolar-membrane electrodialysis (BPED) cell converts LiCl to LiOH — Faraday's law links the applied current/membrane area/current efficiency to the actual Li+ transport rate (replacing an earlier placeholder fixed-conversion reactor), reporting real cell voltage and electrical power draw — and a forward-feed two-effect evaporator train (vapor from effect 1 heats effect 2) concentrates it to battery-grade LiOH·H2O crystals. Real boiling-point elevation throughout via the Pitzer-electrolyte brine thermo package. Isotherm parameters per the sorption column's own citation (2024 Desalination study, Al-based DLE sorbent). Honesty note: the BPED cell still tracks only the lumped li/lioh solute pair this brine thermo package carries (no first-class Cl-/H+/OH- species), so it produces one outlet stream (the Li+ -> LiOH conversion) rather than a genuine two-compartment acid+base product split — see flowsim/solver/unitops/bped.py for the exact scope.

17 unit ops • BRINE

18 0

View & open

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