Murphree Process Flowsheets & Simulations
Explore 2 validated, solved Murphree simulation flowsheets in MaximaLabs — real components: ethanol, water, propane, n_butane. Open any one directly in your browser.
Solved via: NRTL, PENG-ROBINSON.
Tray efficiency — real trays vs ideal stages
The same ethanol–water column solved with a Murphree vapor tray efficiency of 0.7 instead of ideal equilibrium stages. A real sieve/valve tray never reaches full vapor-liquid equilibrium — the vapor leaving it only partly approaches the equilibrium composition with the tray liquid, mixing in un-equilibrated vapor from the tray below: y = E·K·x + (1−E)·y_below (Murphree 1925). At E = 0.7 each of these 12 trays does 70% of an ideal stage's work, so the overhead ethanol is lower than an equilibrium column of the same tray count would predict — which is exactly why a real column needs more trays than a shortcut (ideal-stage) calculation says. Both HYSYS and Aspen RadFrac expose this per-tray efficiency; set murphree_efficiency back to 1.0 to recover the ideal-stage column. The efficiency auto-selects the component-flow Naphtali-Sandholm solver (the reduced-form solvers carry no explicit per-tray VLE row to apply an efficiency to).
4 unit ops • NRTL
83 0
View & openTray efficiency: 20 real trays are not 20 stages
Every equilibrium column model quietly assumes each tray reaches equilibrium. Real trays do not, and the gap is not small enough to ignore when you are buying a shell. The same depropaniser is solved twice at 20 trays, a 2.5 reflux ratio and a 50/50 split. As 20 equilibrium stages it puts 99.61% propane overhead. As 20 actual trays on the rate-based model it manages 96.63% — the tower is the same height and the separation is measurably worse, because the model applies an efficiency instead of assuming one. Left to itself it derives that efficiency from the feed's relative volatility and liquid viscosity through the O'Connell correlation; give it a stage_efficiency and it uses yours, and at a punishing Murphree 0.5 the overhead drops further to 95.33%. The practical reading: an equilibrium model sized this column at 20 trays and the tray efficiency spent roughly three points of product purity. Size on equilibrium stages and you will under-build the tower — that is what the efficiency is for. Bounded: this applies a single overall efficiency to every tray, which is a screening treatment. It is not a rigorous rate-based column — for genuine two-film Maxwell-Stefan transfer with per-stage interface composition and energy coupling, use nonequilibrium_distillation instead. O'Connell itself is a correlation fitted to commercial tray data, so it carries that scatter.
4 unit ops • PENG-ROBINSON
14 0
View & open