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NRTL VLE Process Flowsheets & Simulations

Explore 4 validated, solved NRTL VLE simulation flowsheets in MaximaLabs — real components: ethanol, water, acetone, ethylene_glycol. Open any one directly in your browser.

Solved via: NRTL.

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Pekin, Illinois, USA

Ethanol–water distillation

An 8-stage column concentrating ethanol overhead toward the azeotrope (the headline demo).

4 unit ops • NRTL

227 3

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Tray efficiency — real trays vs ideal stages

The same ethanol–water column solved with a Murphree vapor tray efficiency of 0.7 instead of ideal equilibrium stages. A real sieve/valve tray never reaches full vapor-liquid equilibrium — the vapor leaving it only partly approaches the equilibrium composition with the tray liquid, mixing in un-equilibrated vapor from the tray below: y = E·K·x + (1−E)·y_below (Murphree 1925). At E = 0.7 each of these 12 trays does 70% of an ideal stage's work, so the overhead ethanol is lower than an equilibrium column of the same tray count would predict — which is exactly why a real column needs more trays than a shortcut (ideal-stage) calculation says. Both HYSYS and Aspen RadFrac expose this per-tray efficiency; set murphree_efficiency back to 1.0 to recover the ideal-stage column. The efficiency auto-selects the component-flow Naphtali-Sandholm solver (the reduced-form solvers carry no explicit per-tray VLE row to apply an efficiency to).

4 unit ops • NRTL

140 0

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Acetone
Water
Reference model (ChemSep)

Acetone–water distillation

A 12-stage column recovers acetone overhead from a dilute aqueous solvent-recovery feed — a common industrial acetone/solvent-recycling duty.

4 unit ops • NRTL

232 0

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Ethanol
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Glycol Recycle
Reference model (Luyben 2006)

Extractive distillation (ethanol/water with ethylene glycol)

Near-azeotropic ethanol/water (85 mol% ethanol) can't be pushed past the 89 mol% azeotrope by ordinary distillation. A heavy, high-boiling entrainer (ethylene glycol) fed near the top of the column raises water's relative volatility enough to pull overhead ethanol past the azeotrope in one pass; a second column then strips water overhead from the glycol, regenerating it as the bottoms product. The classic extractive-distillation textbook case (Luyben, Ind. Eng. Chem. Res. 2006, 45, 4625).

7 unit ops • NRTL

254 0

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