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Steam cracking Process Flowsheets & Simulations

Explore 3 validated, solved Steam cracking simulation flowsheets in MaximaLabs — real components: ethane, ethylene, h2, n_heptane, methane, propylene. Open any one directly in your browser.

Solved via: PENG-ROBINSON.

FEED
Crack
Quench
COMP
Cool2
SEP
H2tail
feed
dist
btms
Qc
Qr
COL
Ethylene
Ethane
Mont Belvieu, Texas, USA

Ethane steam cracker

A simplified thermal-cracking train: an equilibrium reactor converts ethane to ethylene + H₂ at furnace conditions (1100 K), then a quench, compression, and a cold flash strip the H₂ tail gas before a C₂ splitter separates ethylene product from unconverted ethane. An equilibrium reactor is used here rather than the kinetic reactor because the latter's concentration term always uses a liquid-phase density (a real gap for a vapor-phase reaction at 1100 K) — noted, not fixed, out of scope for this example. The C₂ splitter needs many stages and high reflux since ethylene/ethane relative volatility is modest. From the ChemSep casebook (ethane cracker).

10 unit ops • PENG-ROBINSON

232 0

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Naphtha FEED
FUEL GAS
process
fuel
proc
flue
Furnace
FLUE Stack
Crack1
Crack2
Crack3
TLE Quench
Primary COOL
Primary SEP
Pygas Heavy
Compressor1
COOL C1
KO1
KO1 Liquid
Compressor2
COOL C2
KO2
KO2 Liquid
Acetylene Hydro
Chill Demeth
Coldflash
TAIL GAS
feed
dist
btms
Qc
Qr
Deeth
feed
dist
btms
Qc
Qr
C2 Splitter
Ethylene Product
Ethane Byproduct
feed
dist
btms
Qc
Qr
Depropanizer
Propylene Product
C4 Butadiene Product
Steam cracker complex, e.g. Linde-licensed olefins plants

Naphtha steam cracker: furnace, quench, compression, cryo train

The full ethylene-plant process shape (steam-methane-cracking's headline technology, e.g. Linde's steam cracking line): a fired-heater convection preheat, a three-reactor lumped pyrolysis furnace, a transfer-line-exchanger quench, a primary fractionator pulling off pyrolysis gasoline, two-stage compression with interstage knockouts, selective acetylene hydrogenation, and a cryogenic cold train (cold-flash light-gas rejection, deethanizer, C₂ splitter, depropanizer) delivering four real products — ethylene, propylene, a butadiene-rich C₄ cut, and a pygas/heavy-ends byproduct — plus an H₂/CH₄-rich tail gas and two knockout condensate streams.

30 unit ops • PENG-ROBINSON

244 2

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FEED
Electric Furnace
Crack
Quench
COMP
Cool2
SEP
H2tail
feed
dist
btms
Qc
Qr
COL
Ethylene
Ethane
BASF Verbund site, Ludwigshafen, Germany

Electrically heated ethane cracker (Linde/BASF/SABIC STARBRIDGE concept)

The same ethane-to-ethylene thermal cracking chemistry as ethane-cracker, but with the furnace's radiant-coil heating supplied by an electric heater instead of a fuel-gas-fired one — the real distinguishing feature of Linde's STARBRIDGE technology (demonstrated at industrial scale with BASF and SABIC at Ludwigshafen, 2024): resistive heating elements replace burners, transferring heat to the process coils by radiation 'in a configuration similar to conventional furnaces,' eliminating the furnace's own combustion-derived CO₂ emissions (upstream grid emissions aside). Modeled here as a plain electric heater node (no fuel-gas inlet, no flue gas, no combustion stoichiometry) in place of fired_heater's combustion-fired duty — the honest difference this technology actually is: identical process-side thermal duty and cracking chemistry, a different (electric) heat source with no direct-combustion byproduct stream. Linde's own proprietary heating-element/coilbox design, materials, and thermal efficiency figures are not published and are not fabricated here; the furnace's computed duty is a genuine energy-balance result (electric heater → real Q required to bring the feed to cracking temperature), not a marketing number.

11 unit ops • PENG-ROBINSON

189 1

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