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Styrene Process Flowsheets & Simulations

Explore 2 validated, solved Styrene simulation flowsheets in MaximaLabs — real components: ethylbenzene, styrene, h2, ethylene, benzene. Open any one directly in your browser.

Solved via: PENG-ROBINSON.

Ebfeed
RXN
SEP
Offgas H2
feed
dist
btms
COL
Ethylbenzene Recycle
Styrene Product
Reference model (Vasudevan 2009)

Styrene monomer via ethylbenzene dehydrogenation

Ethylbenzene dehydrogenates over an equilibrium/conversion reactor to styrene monomer plus hydrogen — the endothermic reaction that supplies the world's polystyrene/SBR-rubber feedstock. A downstream column recovers unreacted ethylbenzene overhead for recycle while polymer-grade styrene leaves the bottoms. Vasudevan design, Ind. Eng. Chem. Res. 2009, 48, 10941 (Figure 15.1).

7 unit ops • PENG-ROBINSON

17 0

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FEED
Alkrx
COOL
feed
dist
btms
Alkcol
Light ENDS
Reheat
Dehydro
SEP
Offgas H2
feed
dist
btms
Stycol
Ethylbenzene Product
Styrene Product
Styrene chain, Antwerp, Belgium

Integrated styrene chain: benzene to styrene monomer

The full two-step styrene chain connected as one flowsheet rather than two standalone process snippets: benzene alkylated with ethylene to ethylbenzene, purified in a recovery column, then fed directly to the dehydrogenation reactor that makes styrene monomer. The unreacted ethylbenzene the dehydrogenation column recovers is reported as its own product stream rather than recycled back onto the alkylation feed (an honest simplification — closing that loop needs a torn-recycle edge back into ALKCOL, which the plant does but this flowsheet does not).

12 unit ops • PENG-ROBINSON

17 0

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