MaximaLabs
All unit operations

Decanter simulation

1 liquid inlet -> light + heavy liquid (LLE)

Governing equations

The exact equations the solver works for a decanter — the same math shown in the app's "Theory" panel, not a black box.

γiIxiI=γiIIxiII(iso-activity liquid-liquid equilibrium, predictive UNIFAC)\gamma_i^{I} x_i^{I} = \gamma_i^{II} x_i^{II}\quad(\text{iso-activity liquid-liquid equilibrium, predictive UNIFAC})
zi=(1β)xiI+βxiII,i(xiIxiII)=0z_i = (1-\beta)\,x_i^{I} + \beta\,x_i^{II},\qquad \sum_i (x_i^{I} - x_i^{II}) = 0
Tout=Tin,Pout=Pin(isothermal split; no splitpass-through, never a fabricated one)T_{out} = T_{in},\quad P_{out} = P_{in}\quad(\text{isothermal split; no split} \Rightarrow \text{pass-through, never a fabricated one})
ziz_i
overall feed mole fraction of component i
xiI,xiIIx_i^{I}, x_i^{II}
mole fractions in the light (I) and heavy (II) liquid layers
γiI,γiII\gamma_i^{I}, \gamma_i^{II}
UNIFAC activity coefficients in each layer — equal activities, not equal compositions, is what equilibrium means here
β\beta
fraction of the feed reporting to the heavy phase [0..1]
T,PT, P
temperature [K] and pressure [Pa] — unchanged; a decanter separates, it does not heat or drop pressure

Parameters

(no params) — the split is purely thermodynamic: an isothermal UNIFAC liquid-liquid flash at the feed's own T and P. Outlets/edges in order: light, heavy (by density). A feed that does not split passes through as the heavy phase with a warning.

Example flowsheets that use it

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