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Cobalt/nickel solvent extraction (D2EHPA)

Solvent extractionHydrometallurgyCobaltNickelBattery metalsD2EHPA
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A laterite leach liquor (Co/Ni/Mg in dilute sulfate solution) meets a D2EHPA-in-kerosene organic phase across a 20-stage countercurrent extraction circuit run at pH 5.2 — the real industrial operating window (e.g. Bulong, Murrin Murrin, Western Australia) that exploits the ~1 pH-unit gap between Co and Ni's D2EHPA extraction isotherms: Co extracts into the organic while Ni (and Mg gangue) are rejected to the raffinate. The loaded organic then meets fresh dilute-acid strip liquor across a 10-stage strip circuit at pH 1.0 (well below Co's isotherm), reversing the equilibrium to recover a concentrated cobalt strip liquor and regenerate barren organic. Real pH-isotherm chemistry throughout (thermo/organophosphorus_extraction.py), not a fitted shortcut K_D. Honesty note: the regenerated organic and strip liquor aren't recycled back upstream (an open-loop v1, same posture as this session's other new cycle examples) — a real plant recycles both; strip_stage's distribution_coefficients is the numeric inverse of the same isotherm (1/D_Co at pH 1.0 = 1e8, i.e. strongly favors the aqueous phase) since extraction_column.py's ph= mode always assumes the aqueous-feed/organic-solvent extraction direction, not reverse stripping.

The flowsheet

The solved topology — every unit op's real duty, conversion, or split, read straight off a genuine converged solve.

Leach Liquor
Organic FEED
feed
solv
ext
raff
Extract Stage
NI Raffinate
Strip Liquor
feed
solv
ext
raff
Strip Stage
Cobalt Strip Liquor
Regenerated Organic

The stream table

Every stream's flow, temperature, pressure, and composition — real converged numbers, not placeholders.

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