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EDC pyrolysis furnace: 1,2-dichloroethane to vinyl chloride monomer

EDCVinyl chlorideVCMPVCPyrolysis furnace
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The balanced-process route to PVC's monomer: 1,2-dichloroethane (EDC) thermally cracks in a fired furnace to vinyl chloride (VCM) + HCl (C2H4Cl2 -> C2H3Cl + HCl, exactly mass-balanced), the HCl is stripped overhead in a distillation column (recovered pure -- it's recycled to the plant's oxychlorination unit in a real balanced VCM process, not modeled here), and a second column separates VCM product from unconverted EDC (also recycled in a real plant). Unlike Linde's proprietary furnace internals (tube metallurgy, coking-cycle length, radiant-zone geometry), EDC pyrolysis chemistry itself is standard, widely published petrochemical engineering (Kirk-Othmer and equivalent references), not proprietary Linde IP -- so this is built directly from the real reaction and typical single-pass conversion (~50-55%, a widely cited industrial range for this process, not a specific plant's exact figure), the same 'illustrative, representative, not literature-pinned to one source' posture used throughout this codebase's cracking-furnace examples. Honesty note: a real EDC/VCM plant recycles both the HCl (to oxychlorination) and unconverted EDC (back to the furnace); both leave as standalone product streams here since neither the oxychlorination unit nor a recycle loop is modeled in this example.

The flowsheet

The solved topology — every unit op's real duty, conversion, or split, read straight off a genuine converged solve.

EDC FEED
Pyrolysis
Quench
feed
dist
btms
HCL COL
HCL Product
feed
dist
btms
VCM COL
VCM Product
Unconverted EDC

The stream table

Every stream's flow, temperature, pressure, and composition — real converged numbers, not placeholders.

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