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Ethanol-water rectifier (UNIQUAC)

DistillationUNIQUACEthanolAzeotropeActivity model
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The ethanol-water rectifier on UNIQUAC — Abrams and Prausnitz's local-composition model with its surface and volume parameters, here on the one binary the package carries regressed parameters for (every other pair falls back to UNIFAC, which the package description says). 30 mol% feed, 20 stages, reflux 2.5, 40% distillate: 75 mol% ethanol overhead and ethanol-free water in the bottoms at 5.7 MW. The cut is kept at 0.40 on purpose: at 0.32 the spec asked for a 94% distillate past the 89.4% azeotrope and the column reported exactly that, and at 0.36 it pinched a hair short of it (balance 5e-3). Compare with the same column on NRTL and Wilson to see how much three regressed models agree on one well-measured pair — a few tenths of a percent in the distillate.

The flowsheet

The solved topology — every unit op's real duty, conversion, or split, read straight off a genuine converged solve.

FEED
feed
dist
btms
Qc
Qr
COL
Distillate
Bottoms

The stream table

Every stream's flow, temperature, pressure, and composition — real converged numbers, not placeholders.

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