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MEG/EG complex, Jubail, Saudi Arabia

How to simulate ethylene glycol plant: closed water loop + multi-effect evaporator dehydration

The water-integrated evolution of the fiber-grade MEG plant. Two changes turn the once-through EO/glycol chain into a real, water-economical process: (1) the recovered process water is RECYCLED back to the hydration reactors through a purge splitter. A pure recycle is inventory-singular (reactors are keyed on the shrinking EO pool, so water consumption is fixed regardless of how much water circulates), so an 8% purge pins the loop and makes it well-posed, cutting fresh water makeup from 10 to ~1.75 mol/s (a >80% reduction). (2) The bulk dehydration is done by a genuine TWO-EFFECT EVAPORATOR TRAIN (forward-feed, real steam economy: effect 1's low-temperature vapor is the heating steam for effect 2) doing rigorous (P,H)-flash water removal, rather than a single spec-based split. The recycle converges through the solver's Wegstein tearing (~15 outer passes) and MEG still comes out fiber-grade (>=99.9%). HONEST SCOPE: the reaction chemistry is rigorous stoichiometry (real atom balances, ~90/9/1 selectivity) and the evaporators are real energy-balanced flash effects -- but flash evaporation CANNOT reach glycol dryness without slipping glycol into the overhead vapor (MEG has a real vapor pressure at 90 C), so the evaporators run cool and only pre-concentrate. An overhead knockout returns the ~1-2% slipped glycol to the product (no yield loss), and a final vacuum-refining polish (still a spec-based split, representing the refluxed dehydration column a flash cannot replicate) removes the last water. This mirrors a real MEG plant's multi-effect-evaporator + vacuum-refining dehydration section. The product columns remain spec-based (a converged 99.9% fiber-grade MEG column is not tractable under Peng-Robinson here -- the MEG/DEG relative volatility is too narrow for the wide-boiling MESH path).

Ethylene FEED
O2 FEED
MIX0
Epoxrx
Combrx
Cool0
Condense
Purge GAS
Water Makeup
MIX1
RXN1
RXN2
RXN3
Cool1
Degas
Offgas
MP Steam
feed
steam
conc
vapor
cond
Evap1
feed
steam
conc
vapor
cond
Evap2
Steam COND
OH MIX
OH KO
Dehydrate
GLY MIX
COND Water
Water Split
Water Purge
MEG COL
MEG Product
DEG COL
DEG Product
TEG Product
  1. 1
    Open the ready-made model

    Open the "Ethylene glycol plant: closed water loop + multi-effect evaporator dehydration" model in the MaximaLabs workspace — no install, no license. It loads live on the canvas, ready to edit and run.

  2. 2
    Confirm the thermodynamics

    This process is modeled with the PENG-ROBINSON property package over ethylene, oxygen, ethylene_oxide, co2, water, ethylene_glycol, diethylene_glycol, triethylene_glycol — already selected, so the phase equilibrium and enthalpy are physically consistent from the first run.

  3. 3
    Review the flowsheet

    The flowsheet chains 5× COND Water, 5× RXN3, 2× Cool1, Condense, 5× DEG COL, 2× Evap2, Water Split. Every block is a real, solvable unit op you can reconfigure on the canvas.

  4. 4
    Run the simulation

    Click Run. The deterministic solver converges the material and energy balances (recycles included) and fills the live stream table — the AI never invents a number.

  5. 5
    Read the results and iterate

    Inspect the converged streams, tweak a spec, and re-run — or ask the AI copilot to explain a result or diagnose a failed solve in plain English.

What you'll build
Thermodynamics
PENG-ROBINSON
Components
ethylene, oxygen, ethylene_oxide, co2, water, ethylene_glycol, diethylene_glycol, triethylene_glycol
Unit operations
5× COND Water5× RXN32× Cool1Condense5× DEG COL2× Evap2Water Split
Open this model in the workspace

Opens live on the canvas — free, no install.

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