MaximaLabs

Direct lithium extraction, against a wall of magnesium

Lithium loaded selectively off a Salar brine, concentrated, converted to hydroxide by electrodialysis and crystallized to battery grade.

Selective Li loading against a ~290:1 Mg/Li backgroundBPED converting LiCl to LiOH by Faraday's lawMSMPR crystallizer — population balance sets the crystal size
Salar brine
Li sorption column
Spent brine
Eluent water
Eluate mix
RO pump
Reverse osmosis
RO permeate
Bipolar-membrane ED
Steam
Evaporator 1
Evaporator 2
Condensate 1
Condensate 2
LiOH crystallizer
LiOH·H₂O
Mother liquor

The actual dark-mode canvas: brine through a selective lithium sorbent, the eluate concentrated by reverse osmosis, converted to hydroxide by bipolar-membrane electrodialysis, then double-effect evaporated and crystallized to battery-grade LiOH·H₂O.

Rejecting magnesium is the whole problem

Salar brines carry magnesium at a couple of hundred times the lithium, and it is chemically similar enough that ordinary precipitation cannot separate them — evaporation ponds take eighteen months for exactly this reason. A selective sorbent does it in one pass, and the crystallizer at the far end is solved on a real population balance, so the product crystal size is computed rather than assumed.

selectivity: qLi/cLiqMg/cMg1(what makes DLE possible at all)\text{selectivity: } \frac{q_{\mathrm{Li}}/c_{\mathrm{Li}}}{q_{\mathrm{Mg}}/c_{\mathrm{Mg}}} \ggg 1 \quad \text{(what makes DLE possible at all)}
n˙LiOH=IηF(BPED conversion by Faraday’s law)\dot n_{\mathrm{LiOH}} = \frac{I\,\eta}{F} \quad \text{(BPED conversion by Faraday's law)}
nt+GnL=Bnτ(MSMPR population balance)\frac{\partial n}{\partial t} + G\frac{\partial n}{\partial L} = B - \frac{n}{\tau} \quad \text{(MSMPR population balance)}

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Lithium sorption (DLE)

Selective Li+ loading off a high-magnesium brine, eluted to a Li-rich strip liquor.

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Mixer

Combines multiple streams into one, closing the mass and energy balance.

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Pump

Raises liquid pressure; a flow-dependent head curve drives it in pressure-driven mode.

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Membrane (RO)

Solution-diffusion rating model, bounded by van't Hoff osmotic pressure.

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Bipolar-membrane electrodialysis

LiCl to LiOH by Faraday's law — the conversion stage of a direct-lithium-extraction train.

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Evaporator (effect)

Process feed against heating steam — concentrated liquid, vapour boil-off and steam condensate in one balance.

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Crystallizer

MSMPR population balance — nucleation and growth set the mean crystal size.

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Live plant integration

Stream sorbent loading, RO permeate conductivity and crystallizer supersaturation from the plant's OPC-UA server into this flowsheet's twin comparison — sorbent capacity fades over cycles, and the solved loading is what makes the fade measurable.

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