MaximaLabs

Hydrogen liquefaction, and the step helium doesn't need

A Linde-Hampson JT recycle with catalytic ortho-para conversion — without which the stored liquid boils itself away.

Closed Linde-Hampson recycle, converged as a real loopCatalytic ortho-para conversion modelled explicitlyThe spin-isomer step that decides whether LH₂ survives storage
H₂ feed
Recycle mix
Compressor
Aftercooler
Pre-cooler
Ortho-para converter
JT valve
Flash drum
Liquid H₂

The actual dark-mode canvas: hydrogen compressed, cooled, catalytically converted toward the para spin isomer, then throttled and flashed to liquid — with the cold vapour returned to the compressor suction as a real closed recycle.

The conversion heat exceeds the latent heat

Normal hydrogen is ~75% ortho; at 20 K equilibrium is ~99.8% para. Liquefying first and converting later releases more heat than the latent heat of vaporization, so an unconverted tank boils itself empty. That is why a catalyst bed sits inside the cold box, and why this flowsheet models it as its own unit op rather than folding it into an efficiency.

ortho-H2para-H2,xparaeq(20 K)0.998\text{ortho-}\mathrm{H_2} \rightleftharpoons \text{para-}\mathrm{H_2}, \qquad x_{\text{para}}^{\,eq}(20\text{ K}) \approx 0.998
Δhop703 J/mol>Δhvap(H2)452 J/mol\Delta h_{\,o\to p} \approx 703\ \mathrm{J/mol} > \Delta h_{vap}(\mathrm{H_2}) \approx 452\ \mathrm{J/mol}
hin=hout(JT throttle into the two-phase region)h_{in} = h_{out} \quad \text{(JT throttle into the two-phase region)}

Unit ops shipped for this vertical

Mixer

Combines multiple streams into one, closing the mass and energy balance.

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Compressor

Polytropic compression to pipeline/process pressure.

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Heater / cooler

Duty- or outlet-condition-specified energy-balance stage.

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Ortho-para H2 converter

Catalytic spin-isomer shift toward equilibrium — the step that stops liquid hydrogen boiling itself away.

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Throttle valve

Isenthalpic Joule-Thomson expansion — the same relation cryogenic JT liquefaction relies on.

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Flash drum

Single-stage vapor-liquid equilibrium split at a fixed temperature/pressure.

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Live plant integration

Stream compressor discharge, converter bed temperatures and flash-drum level from the liquefier's OPC-UA server into this flowsheet's twin comparison — an under-converted para fraction is invisible on a temperature trend and shows up weeks later as boil-off.

See the Digital Twin platform →

Try it yourself

  • Closed Linde-Hampson recycle converged as a real loop
  • Conversion heat exceeds the latent heat of vaporization
  • The spin-isomer step modelled as its own unit op

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