MaximaLabs

Ethanol dehydration, past the azeotrope

A hydrophilic pervaporation membrane pulling water out of near-azeotropic ethanol — the separation relative volatility cannot do.

Crosses the 89 mol% ethanol-water azeotropeSelective permeation, not a relative-volatility splitNo entrainer, no second column
Near-azeotropic ethanol
Pervaporation membrane
Anhydrous ethanol
Water permeate

The actual dark-mode canvas: near-azeotropic ethanol fed to a hydrophilic membrane that permeates water preferentially, drying the retentate past the azeotrope.

Why this crosses what distillation cannot

At the azeotrope vapour and liquid have the same composition, so relative volatility gives a column nothing to work with. A membrane separates on permeability instead, which has no such pinch — the reason pervaporation exists at all.

Ji=Pi(xiγipisatyipperm)(solution-diffusion driving force)J_i = \frac{P_i}{\ell}\bigl(x_i\gamma_i p_i^{sat} - y_i p_{\text{perm}}\bigr) \quad \text{(solution-diffusion driving force)}
αH2O/EtOH=yH2O/xH2OyEtOH/xEtOH1\alpha_{\mathrm{H_2O/EtOH}} = \frac{y_{\mathrm{H_2O}}/x_{\mathrm{H_2O}}}{y_{\mathrm{EtOH}}/x_{\mathrm{EtOH}}} \gg 1
at the azeotrope yi=xi — distillation stops, permeation does not\text{at the azeotrope } y_i = x_i \text{ — distillation stops, permeation does not}

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Pervaporation membrane

Selective permeation to a vapour permeate — crosses an azeotrope distillation cannot.

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Live plant integration

Stream permeate pressure, feed temperature and retentate water content from the skid's OPC-UA server into this flowsheet's twin comparison — a membrane losing selectivity shows as a widening gap from the solved retentate long before a lab sample confirms it.

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