MaximaLabs

Corn Wet Milling

Starch slurry to high-fructose corn syrup — saccharification, isomerisation, SMB enrichment and syrup evaporation.

Isomerase lands at its real 42% equilibriumSyrup to 77 wt% — commercial HFCS specBoiling-point elevation from a real sugar activity model
Starch slurry (35 wt%)
Saccharification
Isomerisation
Desorbent water
SMB enrichment
Raffinate (glucose recycle)
Effect 1
Effect 2
HFCS syrup (77 wt%)
Vapour

The actual dark-mode canvas: a starch slurry saccharified to glucose, part-isomerised to fructose, enriched by simulated moving bed, and concentrated to syrup in a two-effect evaporator.

Why the syrup evaporator needs a sugar activity model

Glucose isomerase stops at about 42% fructose — that is its equilibrium, and it is precisely why an SMB sits downstream: the reaction cannot reach HFCS-55 on its own. The evaporator is the subtler one. Model the sugars as inert solids and it is bimodal: it either does not boil or boils to dry sugar, because nothing raises the boiling point as the liquor concentrates. The Norrish activity model supplies that elevation — 7 K at 71 wt%, matching published syrup data — and syrup concentration becomes a smooth, controllable function of steam.

lnaw=lnxwK(1xw)2(Norrish — water activity in a syrup)\ln a_w = \ln x_w - K\,(1 - x_w)^2 \quad \text{(Norrish — water activity in a syrup)}
aw(x)Pwsat(T)=P(the elevated boiling point)a_w(x)\,P^{sat}_w(T) = P \quad \text{(the elevated boiling point)}
r=vmax[S]Km+[S](Michaelis-Menten — saccharification, isomerisation)r = \frac{v_{max}\,[S]}{K_m + [S]} \quad \text{(Michaelis-Menten — saccharification, isomerisation)}

Unit ops shipped for this vertical

SMB chromatography

Simulated moving bed via its true-moving-bed equivalent — continuous, not a batch column.

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Evaporator (effect)

Process feed against heating steam — concentrated liquid, vapour boil-off and steam condensate in one balance.

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Live plant integration

Stream evaporator steam rate, effect pressures and syrup density from the plant historian into this flowsheet's twin comparison — syrup concentration is the controlled variable the whole evaporator train exists to hold, and steam per tonne of solids is where the energy bill is won or lost.

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Try it yourself

  • Isomerase at its real 42% equilibrium
  • Syrup to 77 wt% — commercial HFCS spec
  • Real boiling-point elevation from a sugar activity model

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