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NGL recovery plant, Permian Basin, Texas, USA

Deep ethane recovery with propane-refrigerated feed chilling — a PENG-ROBINSON process flowsheet

Associated gas is chilled by an external propane refrigeration package before a demethanizer recovers ethane and heavier as NGL bottoms from a methane-rich residue gas overhead — the cryogenic-chilling role Ortloff's CCS/GSP processes play ahead of the turboexpander in a real deep-ethane-recovery plant. The mechanical refrigeration loop itself (compressor/condenser/valve) isn't separately modeled here; the chiller's duty is represented directly as the feed's cooled outlet temperature (the same honest-simplification pattern used for LNG cold-box examples elsewhere in this library).

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FEED
Chill
feed
dist
btms
Demeth
Residue GAS
NGL Product
What this showcases
  • Rigorous PENG-ROBINSON thermodynamics, solved by the same engine every simulation runs on.
  • 2 unit operations modeled: Chill, Demeth.
  • Focus areas: NGL recovery, Cryogenic, Refrigeration, Deep ethane recovery.
Specification
Thermodynamics
PENG-ROBINSON
Components
methane, ethane, propane, n_butane
Unit operations
ChillDemeth
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Python SDK

Reproduce this exact result from Python — the real client.get_example() → run_and_wait() path, not a mockup.

from flowsim.sdk import FlowSimClient

client = FlowSimClient()
example = client.get_example("ortloff-ccs-ngl-recovery")
sim = client.create_simulation(example["title"], example["flowsheet"])
result = client.run_and_wait(sim["id"])

print(result["status"])              # "converged"
streams = client.streams(sim["id"])

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Gas processing plant, Permian Basin, Texas, USA

Cryogenic NGL recovery (GERG-2008 EoS)

A natural-gas dew-point-control / NGL knockout run on the GERG-2008 reference equation of state — the multiparameter Helmholtz model the LNG and custody-transfer industries use because cubic EoS (Peng-Robinson/SRK) are off by several percent on cryogenic natural-gas density. Rich pipeline gas is chilled, let down across a Joule-Thomson valve into the two-phase region, and flashed cold to drop out an NGL liquid (propane/butane-rich) from the methane sales gas. The value is accuracy: on this flowsheet GERG predicts an NGL liquid density ~10% different from Peng-Robinson at cryogenic conditions — enough to change vessel and exchanger sizing. Implemented via CoolProp's multiparameter Helmholtz mixture model (GERG-2008 binary reducing/departure functions), a validated implementation — not a hand-transcription of GERG's thousands of coefficients. Scope: natural-gas / light-hydrocarbon components only (every species must be a CoolProp fluid); see.

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Cold-separator NGL recovery / dew-point control

A rich natural gas is chilled in the gas/gas exchanger + propane-chiller train (lumped here as one cold box) to -33 degC and let into a cold separator. The heavy hydrocarbons (C3+) drop out as a raw NGL liquid, leaving a leaner sales gas that meets its hydrocarbon dew-point spec — so no more liquid forms as the gas cools in the export pipeline. The cold separator is modelled as an adiabatic flash fed by the chiller, so the single knob (the chill temperature) drives both the NGL recovered and the refrigeration duty: colder recovers more NGL but costs more refrigeration (the built-in sensitivity). Peng-Robinson handles the hydrocarbon VLE; the companion gas-conditioning utilities (hydrate risk, water content, Joule-Thomson choke cooling, and compressor sizing for the sales-gas recompression) quantify the rest of the plant around it.

Permian Basin, Texas, USA

Associated gas conditioning

Field gas is compressed, chilled below its dew point, and flashed to knock out NGL/condensate — the sales-gas vs. liquids split every midstream gathering plant runs (Peng-Robinson).

Reference model (ChemSep)

Propane refrigeration cycle

A single-stage vapor-compression refrigeration loop: propane vapor is compressed, condensed to subcooled liquid, throttled through a valve, and superheated back to vapor in the evaporator before recycling — a small makeup feed and purge close the mass balance (inspired by ChemSep's Refrigeration_* reference cases).

Reference model (ChemSep)

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A single-stage vapor-compression refrigeration loop using ammonia — the classic industrial (rather than HFC) refrigerant — condensed to subcooled liquid, throttled through a valve, and superheated back to vapor in the evaporator before recycling (inspired by ChemSep's Refrigeration_Ammonia-30C reference case).

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Ammonia refrigeration (−30 °C)

A closed single-stage ammonia vapor-compression cycle serving a −30 °C load: compressor → ambient condenser → JT valve → evaporator. The charge is set via tear_specs; metrics give duty and work (COP ≈ 2). From the ChemSep casebook (Refrigeration_Ammonia-30C).

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